Reacts with nitrogen oxides at about 180; the reaction becomes explosive. Vapors may travel to source of ignition and flash back. Incompatible with liquid oxygen. Formaldehyde, 37% w/w Safety Data Sheet according to Federal Register / Vol. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Formaldehyde: off-gas : 200-001-8: Section 3 - Hazards Identification EMERGENCY OVERVIEW. Avoid dust formation. In people sensitized to formaldehyde, late asthmatic reactions may be provoked by brief exposures at approximately 3 ppm. Commercial formaldehyde-alcohol solutions are stable. Wash hands before breaks and at the end of workday. a. (USCG, 1999). Studies produced a weak association (limited evidence) between adverse human female reproductive effects and occupational exposure. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Consult an expert! 1.1. Solutions splashed in eyes have caused injuries ranging from severe, permanent corneal opacification and loss of vision to minor discomfort. Will burn if involved in a fire and give off noxious fumes (e.g. Cat. Maintain open airway and assist ventilation if necessary. These reactions are activated by light, catalyzed by salts of transition metals, and are autocatalytic (catalyzed by the products of the reaction). View product specific information, MSDS, References and Buying FAQ. Safety Data Sheet Sodium Formaldehyde Bisulphite Solution SDS 26/7 Page n. 3 of 8 None in particular. Liq. endobj Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58 & 1272/2008/EC Standards SDS Revision: 5.2 SDS Revision Date: 7/20/2018 5. When heated, irritant formaldehyde gas evolved from solution. Keep upwind to avoid inhalation of gases, vapours, fumes and smoke. Odour Threshold: 0,05 – 0,125 ppm (Formaldehyde) pH: 2,8 – 4,0 at 20°C Melting point: < -15°C Boiling point/boiling range: 93-96°C at 1.013 hPa Flash point: 62°C Method: c.c Evaporation rate: No information available Flammability (solid, gas): No information available When heated, irritant formaldehyde gas evolved from solution. Turn off gas at source if possible. Compound will polymerize with active organic materials such as phenol. : A registration number is not available for this substance as the substance or its uses are … <> Very few human studies have been done on the adverse reproductive effects from exposure to Formaldehyde. … Absorb with DRY earth or non-combustible material. Product name : Formaldehyde, 10% v/v, Buffered Product code : LC14670 . !#™kîºðp ×]„‘‰åÚt!Ô²#¡óݬ¡eºh­¼íF¨¥ìHh|•°-Bž³ÄEæ1‰¬ú«7\Æ(§’¥½¯ c“‹DÖӋu–­ï.©}ŽÒ{.˜œ'Vç. Product identifier . Special hazards arising from the substance or mixture Do not inhale explosion and combustion gases. P301+P330+P331 IF SWALLOWED: Rinse mouth. Formaldehyde (as urea formaldehyde foam) was extensively used as an insulating material until 1982 when it was banned by the U.S. Consumer Product Safety Commission. Identification::: Supplier's details : Nonflammable Gas Mixture: Formaldehyde 1ppb-999ppm / Nitrogen 99.9001-99. Delayed -- sensitization dermatitis. <>>> The gas is a more dangerous fire hazard than the vapor.The gas mixes well with air, explosive mixtures are easily formed.Dust explosion possible if in powder or granular form, mixed with air. Suppliers of a hazardous chemical to a workplace must provide current safety data sheets. Harmful if inhaled. Very reactive, combines readily with many substances, 40% solution is powerful reducing agent. Product Name : FORMALDEHYDE SOLUTION 37 w/w, stablized with 10-12% methanol Classified as hazardous 1. SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION. AEROBIC: Formaldehyde, present at 100 mg/L, reached 91% of its theoretical BOD in 2 weeks using an activated sludge inoculum at 30 mg/L in the Japanese MITI test which classified the compound as readily biodegradable(1). 2 0 obj Effects in women include menstrual disorders and secondary sterility. Homes in which UFFI was installed many years ago are not likely to have high formaldehyde levels now. Product may generate formaldehyde which can … Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Eye Contact: Vapors cause irritation to the eyes with redness, pain, and blurred visi on. P321 Specific treatment (see ... on this label). Use fluorocarbon water spray, Cellosize and Hycar to diminish vapors. Remove contact lenses, if present and easy to do. A study of hospital equipment sterilizing workers did not report an association between formaldehyde exposure and increased spontaneous abortions. (ERG, 2016), Vapor or dust irritates eyes, mucous membranes, and skin; may cause dermatitis. P260 Do not breathe dust/fume/gas/mist/vapours/spray. Refer immediately for medical attention. Ensure airborne concentrations of formaldehyde do not exceed published exposure limits. Also reacts violently with perchloric acid-aniline, performic acid, nitromethane, magnesium carbonate, and hydrogen peroxide. Workers can inhale formaldehyde as a gas or vapour or absorb it through the skin as a liquid. For precautions see section 2.2. Refer immediately for medical attention. 5.2. Automobile exhaust is a major source of formaldehyde in outdoor air. Large Spill and Leak: Stop leak if it is safe to do so. Use D-Formalizer® pads or F.C.G.® Formaldehyde Control Granules to reduce formaldehyde exposure. Can react with air to give first peroxo acids, and ultimately formic acid. Inhalation. Administer supplemental oxygen, and observe for at least 4 to 6 hours. P270 Do not eat, drink or smoke when using this product. Handle with gloves. Acute exposure to formaldehyde can have a corrosive effect on the respiratory tract, gastrointestinal system, and skin. Advice for fire-fighters: Self-contained breathing apparatus and protective clothing. 1 (H317), Muta. Vapors may cause dizziness or suffocation. May generate toxic formaldehyde gas when heated. It is made of 37% formaldehyde and impurities such as methanol, small amounts of formic acid, aldehydes and ketones. It can cause irreversible eye damage in instances of severe overexposure. P362+P364 Take off contaminated clothing and wash it before reuse. Contact causes white discoloration, smarting, cra cking and scaling. pH 2.8 – 4.0 (25 degrees Celsius) (37% solution) Odour threshold 0.8 – 1ppm Percent volatile … May react with bases (sodium hydroxide, potassium hydroxide, ammonia), and with nitrogen dioxide (explosive reaction around 180\u00b0C). 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